LHL Paint Safety Data Sheet - EGGSHELL
SAFETY DATA SHEET - Eggshell
According to Regulation (EC) No 1907/2006, Article 31
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier: For industrial and professional use only.
Trade name: Acrylic Eggshell
UFI: 9NW4-S0V5-V00G-H9MN
1.2 Relevant identified uses of the substance or mixture and uses advised against: Surface Coating
1.3 Application of the substance / the mixture: Surface Coating
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture.
Classification according to Regulation (EC) No 1272/2008:
The product is not classified, according to the GB CLP regulation.
2.2 Label elements.
Labelling according to Regulation (EC) No 1272/2008: Void
Hazard pictograms: Void
Signal word: Void
Hazard statements: Void
Additional information:
EUH208 Contains 2-methyl-2H-isothiazol-3-one, reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [ECno. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1), 1,2-benzisothiazol-3(2H)-one;1,2-benzisothiazolin-3-one. May produce an allergic reaction.
EUH210 Safety data sheet available on request.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with non-hazardous additions.
Dangerous components:
CAS: 7727-43-7/ EINECS: 231-784-4/ Reg.nr.: Exempt under ANNEX V article 7
Barium sulphate, natural substance with a Community workplace exposure limit >2.5- 10%
CAS: 2634-33-5/ EINECS: 220-120-9/ Reg.nr.: 01-2120761540-60
1,2-benzisothiazol-3(2H)-one;1,2-benzisothiazolin-3-one <1%
Acute Tox. 2, H330; /Eye Dam. 1, H318; /Aquatic Acute 1, H400; Aquatic Chronic 1, H410; / Acute Tox. 4, H302; Skin Irrit. 2, H315; Skin Sens. 1, H317
CAS: 26530-20-1/ EINECS: 247-761-7/ Reg.nr.: 01-2120768921-45-0000/1
2-octyl-2H-isothiazol-3-one <1%
cute Tox. 3, H301; /Eye Dam. 1, H318; /Aquatic Acute 1, H400; Aquatic Chronic 1, H410
CAS: 13463-41-7/ EINECS: 236-671-3
Pyrithione zinc <1%
Acute Tox. 3, H301; /Eye Dam. 1, H318; /Aquatic Acute 1, H400; Aquatic Chronic 1, H410
CAS: 55965-84-9/ EC number: 611-341-5/ Reg.nr.: 01-2120764691-48
Reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H-isothiazol-3-one [EC no. 220-239-6] (3:1) <1%
Acute Tox. 3, H301; Acute Tox. 2, H310; Acute Tox. 2, H330;/ Skin Corr. 1C, H314; Eye Dam. 1, H318; / Aquatic Acute 1, H400; Aquatic Chronic 1, H410; /Skin Sens. 1A, H317
Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly. Remove contaminated clothing.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Do not induce vomiting; call for medical help immediately and show safety datasheet or label.
4.2 Most important symptoms and effects, both acute and delayed.
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed.
Treat symptomatically.
SECTION 5: Firefighting Measures
5.1 Extinguishing media. Suitable extinguishing agents:
Use fire extinguishing methods suitable to surrounding conditions.
5.2 Special hazards arising from the substance or mixture.
No further relevant information available.
5.3 Advice for firefighters:
Protective equipment: Put on breathing apparatus
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Not required.
6.2 Environmental precautions:
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
6.4 Reference to other sections.
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Keep receptacles tightly sealed.
Hygiene measures: Wash hands before breaks and at the end of workday.
Information about fire - and explosion protection: No special measures required
7.2 Conditions for safe storage, including any incompatibilities:
Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed and in a well-ventilated place. Keep away from heat.
7.3 Specific end use(s)
No further relevant information available
SECTION 8: Exposure controls/personal protection
8.1 Control parameters. Additional information about design of technical facilities:
No further data; see section 7.
Ingredients with limit values that require monitoring at the workplace:
7727-43-7 barium sulphate, natural
WEL: Long-term value: 10* 4** mg/m3
*inhalable dust **respirable dust
DNELs
2634-33-5 1,2-benzisothiazol-3(2H)-one;1,2-benzisothiazolin-3-one
Dermal - DNEL - 0.345 mg/day (Con) 0.966 mg/day (Ind)
Inhalative - DNEL - 1.2 mg/m3 (Con) 6.81 mg/m3 (Ind)
55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H- isothiazol-3-one [EC no. 220-239-6] (3:1)
Oral - DNEL - 0.09 mg/day (Con)
13463-41-7 pyrithione zinc
Dermal – DNEL - 0.01 mg/day (Ind)
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls:
Personal protective equipment:
General protective and hygienic measures: Wash hands before breaks and at the end of work.
Respiratory protection: Particulate cartridge filter type when LEV cannot be supplied· Protection of hands: Not required. The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Eye protection: Goggles recommended during refilling
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
General Information - Appearance:
Form: Liquid
Colour: According to product specification
Odour: Characteristic
Odour threshold: Not determined.
pH-value: Not determined.
Change in condition: Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: 100 °C
Flash point: >100 °C
Flammability (solid, gas): Not applicable.
Decomposition temperature: Not determined.
Ignition temperature: Product is not self-igniting.
Explosive properties: Product does not present an explosion hazard.
Explosion limits: Lower: Not determined. Upper: Not determined.
Vapour pressure at 20 °C: 23 hPa
Density at 20 °C: 1.126 g/cm³
Relative density: Not determined.
Vapour density: Not determined.
Evaporation rate: Not determined.
Solubility in / Miscibility with water: Fully miscible.
Partition coefficient: n-octanol/water: Not determined.
Viscosity:
Dynamic at 20 °C: 2,500 mPas.
Kinematic: Not determined.
Solvent content: Organic solvents: 0.2 %Water:55.3 %. Solids content:45.5 %
VOC: Maximum VOC content 13.7g/ltr (EU limit for VOC content is 150g/ltr) EU limit 2004/42 IIA WB (D) 150.
9.2 Other information:
No further relevant information available.
SECTION 10: Stability and reactivity
10.1 Reactivity:
No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
10.3 Possibility of hazardous reactions:
No dangerous reactions known.
10.4 Conditions to avoid:
No further relevant information available.
10.5 Incompatible materials:
No further relevant information available.
10.6 Hazardous decomposition products:
No dangerous decomposition products when stored and handled correctly
SECTION 11: Toxicological information
11.1 Information on toxicological effects.
Acute toxicity: Based on available data, the classification criteria are not met.
LD/LC50 values relevant for classification:
2634-33-5 1,2-benzisothiazol-3(2H)-one;1,2-benzisothiazolin-3-one
Oral - LD50 670 mg/kg (Rat)
Dermal - LD50 >2,000 mg/kg (Rat)
Inhalative - LC50/4 h 0.5 mg/l (Rat)
55965-84-9 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no. 247-500-7] and 2-methyl-2H- isothiazol-3-one [EC no. 220-239-6] (3:1)
Oral - LD50 - 64 mg/kg (Rat)
Dermal - LD50 - 92.4 mg/kg (Rabbit)
Inhalative - LC50/4 h - 0.171mg/l (rat)
13463-41-7 pyrithione zinc
Oral – LD50 – 221 mg/kg (ATE)/ 269 mg/kg (Rat)
Dermal – LD50 - >2,000 mg/kg (Rab)
26530-20-1 2-octyl-2H-isothiazol-3-one
Oral - LD50 - 125 mg/kg (ATE)
Dermal - LD50 - 311 mg/kg (ATE)
Primary irritant effect:
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Serious eye damage/irritation: Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation: Based on available data, the classification criteria are not met.
Additional toxicological information:
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
Reproductive toxicity: Based on available data, the classification criteria are not met.
STOT-single exposure: Based on available data, the classification criteria are not met.
STOT-repeated exposure: Based on available data, the classification criteria are not met.
Aspiration hazard: Based on available data, the classification criteria are not met
SECTION 12: Ecological information
12.1 Toxicity. Aquatic toxicity:
No further relevant information available.
12.2 Persistence and degradability:
No further relevant information available.
12.3 Bioaccumulative potential:
No further relevant information available.
12.4 Mobility in soil:
No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects:
No further relevant information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation: Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents
SECTION 14: Transport information
14.1 UN-Number ADR, ADN, IMDG, IATA: Void
14.2 UN proper shipping name ADR, ADN, IMDG, IATA: Void
14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA: Class Void
14.4 Packing group ADR, IMDG, IATA: Void
14.5 Environmental hazards: Not applicable.
14.6 Special precautions for user: Not applicable.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code: Not applicable.
UN "Model Regulation" Void
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture. Poisons Act.
Regulated explosives precursors: None of the ingredients is listed.
Regulated poisons: None of the ingredients is listed.
Reportable explosives precursors: None of the ingredients is listed.
Reportable poisons: 1336-21-6 | 10 -35 % ammonia solution | 10%
Directive 2012/18/EU
Named dangerous substances: ANNEX I None of the ingredients is listed.
National regulations: Technical instructions (air):
Class: Wasser / Share in % 55.3
Class: NK / Share in % 0.2
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.
Full text of H-Statements referred to under sections 2 and 3:
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Department issuing SDS: Product safety department: LABORATORY
Abbreviations and acronyms:
ADR: Accord relatif au transport international des marchandises dangereuses par route (European Agreement Concerning the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (UK REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bio-accumulative and Toxic
vPvB: very Persistent and very Bio-accumulative
Acute Tox. 4: Acute toxicity – Category 4
Acute Tox. 3: Acute toxicity – Category 3
Acute Tox. 2: Acute toxicity – Category 2
Skin Corr. 1: Skin corrosion/irritation – Category 1
Skin Corr. 1C: Skin corrosion/irritation – Category 1C
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Skin Sens. 1A: Skin sensitisation – Category 1A
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
